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Thiol-ene emulsion step polymerization in a photochemical stirred tank reactor: Molecular weight, cyclization, and fragmentation

ABD

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Industry: Polymers
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Instrument: Vasco

Industry: Polymers

DOI: https://doi.org/10.1002/pol.20220402

Keywords: emulsion polymerization, photopolymerization, photoreactor, step polymerization

Unlike many step polymerizations, the polymerization of bifunctional thiol and alkene monomers can be carried in emulsion to prepare a range of sulfur-containing polymer particles differing markedly from conventional emulsion chain polymers. This study examines how the change of polymerization mechanism affects polymer molecular weight, structure and composition. (318)
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With a single and continuous measurement, VASCO KIN™ gives you access to all characterization data of your reaction (size distribution evolution over time).